Zirconia Hollow Sphere Brick Introduction
Hollow zirconia sphere bricks as a kind of hot sales refractory bricks for furnace application in Rongsheng factory manufacturing with metallurgical industry silicon steel heating furnace lining, oil industry hydrogen furnace, gasification furnace high temperature device insulation lining, hard alloy intermediate frequency furnace insulation lining. Hollow zirconia refractory brick have good properties of high temperature resistance, high strength and stable pore structure. There are high quality refractory, refractory zirconia hollow bricks for sale cheap in RS firebricks company can provide standard size hollow zirconia refractory brick specification and category as well as competitive price & high-grade quality zirconia hollow bricks products, other specification and size of zirconia hollow bricks according to customer requirements,welcome to contact us or email us for free quote or price list.
Zirconia Hollow Sphere Brick Definition
Insulating refractory products made of zirconia hollow spheres as main raw materials. (The main crystalline phase of this brick is cubic zirconia (about 70% to 80% of the mineral phase composition), the refractoriness is greater than 2400 ° C, the apparent porosity is 55% to 60%, and the bulk density is 2.5 to 3.0 g /cm3, the compressive strength is not less than 4.9MPa, the thermal conductivity is 0.23~0.35w/(m•K). Calcium oxide (or yttria, magnesia) is used as a stabilizer, uniformly mixed, melted by arc method. The molten metal is prepared by blowing air. The zirconia fine powder is made of zirconia as raw material, calcium oxide (or cerium oxide, magnesium oxide) is used as a stabilizer, uniformly mixed, electrofused into a molten liquid, and condensed and crushed.
Zirconia Hollow Sphere Brick Features
Zirconia hollow ball brick is a new type of insulation material with high temperature resistance, high strength and stable pore structure.
Zirconium hollow sphere and refractory zirconia hollow brick products have high fire resistance temperature, small bulk density, small heat fusion, low thermal conductivity and strong heat preservation, effectively improve furnace efficiency and shorten production cycle. The long-term use temperature can reach 2200 ℃, the thermal conductivity is about 50% of AL2O3. Hollow zirconia refractory brick is very stable under hydrogen atmosphere, hollow zirconia refractory brick can be used for 30-40% in the hydrogen gas intermediate frequency furnace.
Zirconia Hollow Sphere Brick Specification
Item
|
|
Zirconia Hollow Sphere Brick |
Maximum Use Temp |
℃ |
2200 |
Zr |
% |
98 |
Sio2 |
% |
0.5 |
Fe2o3 |
% |
0.2 |
Bulk Density |
g/cm3 |
3.1 |
Cold Crushing Strength |
Mpa |
8 |
Reburn Rate |
% |
+-2 |
Thermal Expansion Coefficient |
% |
7.8 |
0.2Mpa softening under load refractoriness |
℃ |
1700 |
Zirconia Hollow Sphere Brick Application
The zirconia hollow sphere product is completely made of zirconia hollow spheres, has good high temperature strength and stable pore structure, and is used for heat insulating materials such as medium frequency high temperature furnace, carbon black reaction furnace and tungsten in the furnace cover of ultra high temperature equipment. Bar furnace, molybdenum furnace.
Zirconium oxide hollow ball brick is an excellent thermal insulation refractory product with the highest safe use temperature of 2200 ℃. It is used as a high temperature lining material for direct contact with flame in thermal equipment of metallurgy, petrochemical, electronics and other industries.
Zirconia hollow bricks application in high temperature furnaces above 1750 ℃ or high temperature kiln and kiln furniture.
Zirconia hollow sphere bricks are widely used in non-metallic materials industry, petrochemical, steel smelting, military, electronics industry and other fields. Metallurgical industry silicon steel heating furnace lining, oil industry hydrogen furnace, gasification furnace high temperature equipment insulation lining, hard alloy intermediate frequency furnace insulation lining use hollow zirconia refractory brick.
Zirconia Hollow Sphere Brick Manufacturing Process
1.Mud Casting Zirconia Hollow Bricks Products
❉The zirconia hollow ball brick slurry casting product is an acid mud casting production process.
❉The high-purity zirconia hollow spheres and high-purity calcium hydroxide are used as raw materials, the mixture is finely ground by ZrO2:CaO=95:5, then pressed into blocks, which are kept at 1250 ℃ for 4 hours for stabilization treatment. After the smashing of the stabilized material, 15% of the monoclinic zirconia hollow spherical bricks were added and finely ground to a particle size of less than 3 μm. For example, if the abrasive is finely ground in the iron ball mill, it is also subjected to pickling and iron removal, the metal iron content is less than 0.01%.
❉The zirconia hollow ball brick mud density is required to be 1.9 to 2.1 g/cm3, the pH value is 1.7 to 1.9. Casting with gypsum mold, the mold is placed at a rate of 15%, and the operation method is the same as that of alumina slurry. Immediately after demolding, the product was placed in an electric furnace and incubated at 850 ℃ for 2 h for calcination. After cooling, zirconia hollow brick is sanded and shaped with sandpaper, then fired in a high temperature kiln at 1800 to 1850 ℃ for 4 to 6 hours.
Hot Press Injection Molding Heating Element Zirconia Hollow Bricks Products
❉The zirconia hollow ball brick heating element can be used as a heating element for a high temperature resistance furnace of 1700 ℃ to 2000 ℃.
❉Using high-purity gas valve through zirconium, calcium oxide, cerium oxide, cerium oxide as raw materials can be separately distributed as follows: zirconia hollow ball brick 87%, gas valve calcium 13%, zirconia hollow ball brick 90%, cerium oxide 10%; zirconia hollow ball brick 75%, bismuth oxide 25% three ingredients. The ingredients are finely ground in a ball mill with a particle size of less than 3 μm and more than 80%. Add 6% aqueous solution of polyvinyl alcohol (concentration 10%) to the finely ground powder, mix well and pass through 0.5mm sieve, make the blank at 100MPa pressure, and keep the stable zirconia hollow sphere brick at 1730°C for 4h. Clinker.
❉After the stabilization, the clinker fine grinding particle size is less than 10% of the point of more than 10 μm, and if it is ground in the iron ball mill, it is also subjected to pickling, iron removal, drying, and milling.
❉The wax slurry is prepared by stabilizing zirconia hollow ball brick dry powder 85%, paraffin wax 13.5%, yellow wax 1%, and fatty acid 0.5%. The hot mix is carried out at a temperature of 70 to 80 °C. The wax slurry should be free of powder and no bubbles.
❉The mold is formed on a hot press machine with a metal mold, the temperature of the wax is maintained at 60 to 70 ° C, and the mold release rate is 13% to 15%. The specific operation method is the same as the alumina hot press product.
❉The hot-pressed injection body is made of industrial alumina as a filler in the crucible, refractory zirconia hollow brick is dewaxed by 1200 ° C for 4 h. The product is suspended in a vacuum furnace at a vacuum degree of 1×10-5 kPa (1×10-4 mmHg) and fired at 1650 ° C for 3 hours.
3.Isostatically Shaped Zirconia Hollow Bricks Products
The yttria-stabilized zirconia hollow sphere bricks were used as raw materials, after fine grinding, granulation was carried out, TZP zirconia hollow sphere ceramic grinding media balls were produced by dry pressing on an isostatic press. The medium ball has high density, good toughness, high hardness, high grinding efficiency and good effect, refractory zirconia hollow brick can be used as a grinding medium ball for special refractory materials.
Physical and chemical properties of skateboard bricks for isothermal pressing forming steelmaking and continuous casting: ZrO2≥94%, Y2O3≥1.5%, Y2O3+CaO+MgO%~5%, Al2O3<0.2%, stability 70%~80°C The bulk density is 4.65~5.0g/cm3, the apparent porosity is 15%-20%, the compressive strength is 100MPa, and the thermal shock resistance (1100°C water cooling) is ≥3 times.
Zirconia Hollow Sphere Brick Supplier - RS Firebricks Factory
1.RongSheng refractory bricks have rich refractory raw materials and 20 years experienced in the refractory bricks manufacturing. RongSheng refractory factory bricks can provide specification and category as well as competitive price & high-grade quality firebricks products.
2.RongSheng firebricks have any certificate according to client requirement,such as ISO9001 certificate, CE.
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